Research Themes
Supramolecular chemistry - Macrocyclic chemistry - Host−Guest systems - Cucurbiturils - Cyclodextrins - Crystal Engineering
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Publications
75- Molecular Recognition by Halogen Bonding with Atomic Precision in a Covalent Organic Cage, P.-A. Dupin, J. Yang, E. Antonetti, B. Chatelet, X. Bugaut, J.-P. Dutasta, P. Nava, A.-D. Manick, D. Bardelang, A. Martinez, Angew. Chem. Int. Ed. 2026, e5640364
74- Molecular Adsorbing Host:Guest (MAHG) Crystals: a New Paradigm for Porous Materials? I. Suzana, M. Giorgi, A. Kermagoret, A. Martinez, D. Bardelang, Adv. Funct. Mater. 2026, 36, e17491.
73- Tracking host–guest recognition in cells by a BODIPY•CB[7] complex, F. Liu, H. Xiao, Q. Gao, D. Siri, D. Bardelang, Q. Xing, J. Geng, Chem. Comm. 2025, 61, 6675-6678.
72- Molecular stiffening by macrocycle clustering, H. Yin, Q. Cheng, R. Rosas, S. Viel, M. Giorgi, V. Monnier, L. Charles, D. Siri, D. Gigmes, R. Wang, A. Kermagoret, D. Bardelang, Angew. Chem. Int. Ed. 2025, 64, e202420880.
71- Hypoxia-Initiated Supramolecular Free Radicals Induce Intracellular Polymerization for Precision Tumor Therapy, M. Tang, Z. Yang, X. Tang, H. Ma, B. Xie, J.-F. Xu, C. Gao, D. Bardelang, R. Wang, J. Am. Chem. Soc. 2025, 147, 3488−3499.
70- Viridium: A Stable Radical and its p-Dimerization, H.-P. Jacquot de Rouville, C. Gourlaouen, D. Bardelang, N. Le Breton, J. S. Ward, L. Ruhlmann, J.-M. Vincent, D. Jardel, K. Rissanen, J.-L. Clément, S. Choua, V. Heitz, J. Am. Chem. Soc. 2025, 147, 1823−1830.
69- Controlled Reactivity of Viologens in Alkaline Solutions Via Cucurbit[7]uril Complexation, A. Bossavit, V. Monnier, D. Siri, G. Canard, D. Gigmes, D. Bardelang, A. Kermagoret, Eur. J. Org. Chem. 2024, 27, e202400404.
68- Internal Dynamics and Modular Peripheral Binding in Stimuli-Responsive 3:2 Host:Guest Complexes. H. Yin, R. Rosas, S. Viel, M. Giorgi, V. Monnier, L. Charles, D. Siri, D. Gigmes, Y. Nassar, F. Chevallier, C. Bucher, R. Wang, A. Kermagoret, D. Bardelang, Angew. Chem. Int. Ed. 2024, 63, e202315985.
67- Controlled oligomeric guest stacking by cucurbiturils in water. F. Liu, A. Kriat, R. Rosas, D. Bergé-Lefranc, D. Gigmes, S. Pascal, O. Siri, S. Liu, A. Kermagoret, D. Bardelang, Org. Biomol. Chem. 2023, 21, 9433–9442.
66- The diversity of cucurbituril molecular switches and shuttles. A. Kermagoret, D. Bardelang, Chem. Eur. J. 2023, e202302114.
65- Challenges and opportunities of functionalized cucurbiturils for biomedical applications. H. Yin, Q. Cheng, D. Bardelang, R. Wang, JACS Au 2023, 3, 2356–2377.
64- Preparation and in vitro validation of a cucurbit[7]uril-peptide conjugate targeting the LDL receptor, X. Yang, K. Varini, M. Godard, F. Gassiot, R. Sonnette, G. Ferracci, B. Pecqueux, V. Monnier, L. Charles, S. Maria, M. Hardy, O. Ouari, M. Khrestchatisky, P. Lécorché, G. Jacquot, D. Bardelang, J. Med. Chem. 2023, 66, 8844–8857.
63- A pH- and Metal-Actuated Molecular Shuttle in Water, A. Kriat, S. Pascal, B. Kauffmann, Y. Ferrand, D. Berge-Lefranc, D. Gigmes, O. Siri, A. Kermagoret, D. Bardelang, Chem. Eur. J. 2023, 29, e202300633.
62- Energy-efficient iodine uptake by a molecular host•guest crystal. X. Yang, C. Li, M. Giorgi, D. Siri, X. Bugaut, B. Chatelet, D. Gigmes, M. Yemloul, V. Hornebecq, A. Kermagoret, S. Brasselet, A. Martinez, D. Bardelang, Angew. Chem. Int. Ed. 2022, 61, e202214039.
61- Sequential formation of heteroternary CB[10] complexes, C. Li, A.-D. Manick, Y. Zhao, F. Liu, B. Chatelet, R. Rosas, D. Siri, D. Gigmes, V. Monnier, L. Charles, J. Broggi, S. Liu, A. Martinez, A. Kermagoret, D. Bardelang, Chem. Eur. J. 2022, 28, e202201656.
60- External Complexation of BODIPYs by CB[7] Improves in-Cell Fluorescence Imaging, M. M. Ayhan, E. Özcan, F. Alkan, M. Çetin, İ. Ün, D. Bardelang, B. Çoşut, Materials Adv. 2022, 3, 547-553.
59- Triple stack of a viologen derivative in a CB[10] pair, F. Liu, S. Chowdhury R. Rosas, V. Monnier, L. Charles, H. Karoui, D. Gigmes, O. Ouari, F. Chevallier, C. Bucher, A. Kermagoret, S. Liu, D. Bardelang, Org. Lett. 2021, 23, 5283-5287.
58- Guest exchange by a partial energy ratchet in water, X. Yang, Q. Cheng, V. Monnier, L. Charles, H. Karoui, O. Ouari, D. Gigmes, R. Wang, A. Kermagoret, D. Bardelang, Angew. Chem. Int. Ed. 2021, 60, 6617-6623.
57- Recent advances in supramolecular antidotes, H. Yin, X. Zhang, J. Wei, I. W. Wyman, D. Bardelang, R. Wang, Theranostics 2021, 11, 1513-1526.
56- Macrocycles and related hosts as supramolecular antidotes, H. Yin, D. Bardelang, R. Wang, Trends Chem. 2021, 3, 1-4.
55- Rotaxanating metallo-supramolecular nano-cylinder helicates to switch DNA junction binding, C. A.J. Hooper, L. Cardo, J. S. Craig, L. Melidis, V. Sadovnikova, F. Burkert, R. Egan, A. Garia, M. Pascu, L. Male, N. Hodges, D. Browning, R. Rosas, F. Liu, S. Liu, D. Bardelang, M. J. Hannon, J. Am. Chem. Soc. 2020, 142, 20651-20660.
54- Oligomeric cucurbituril complexes: from peculiar assemblies to emerging applications, X. Yang, R. Wang, A. Kermagoret, D. Bardelang, Angew. Chem. Int. Ed. 2020, 59, 21280-21292.
53- EPR Spectroscopy: A Powerful Tool to Analyze Supramolecular Host•Guest Complexes of Stable Radicals with Cucurbiturils, F. Liu, H. Karoui, A. Rockenbauer, S. Liu, O. Ouari, D. Bardelang, Molecules 2020, 25, 776.
52- A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals, X. Yang, M. Giorgi, H. Karoui, D. Gigmes, V. Hornebecq, O. Ouari, A. Kermagoret, D. Bardelang, Chem. Comm. 2019, 55, 13824-13827.
51- L’électron : une sonde fantastique, D. Bardelang, G. Casano, M. Hardy, H. Karoui, O. Ouari, Act. Chim. 2019, 443, 9−12.
50- A cucurbit[8]uril 2:2 complex with a negative pKa shift, H. Yin, Q. Cheng, R. Rosas, S. Viel, V. Monnier, L. Charles, D. Siri, D. Gigmes, O. Ouari, R. Wang, A. Kermagoret, D. Bardelang, Chem. - Eur. J. 2019, 25, 12552−12559.
49- Triangular regulation of 1:1 cucurbit[8]uril complexes, S. Combes, K. T. Tran, M. M. Ayhan, H. Karoui, A. Rockenbauer, V. Monnier, L. Charles, R. Rosas, S. Viel, D. Siri, P. Tordo, S. Clair, R. Wang, D. Bardelang, O. Ouari, J. Am. Chem. Soc. 2019, 141, 5897−5907.
48- A pH-driven ring translocation switch against cancer cells, Q. Cheng, H. Yin, R. Rosas, D. Gigmes, O. Ouari, R. Wang, A. Kermagoret, D. Bardelang, Chem. Comm. 2018, 54, 13825-13828.
47- Metal actuated ring translocation switches in water, H. Yin, R. Rosas, D. Gigmes, O. Ouari, R. Wang, A. Kermagoret, D. Bardelang, Org. Lett. 2018, 20, 3187-3191.
46- Effects of cucurbit[n]uril (n = 7, 8, 10) hosts on the formation and stabilization of a naphthalenediimide (NDI) radical anion, X. Zhao, F. Liu, Z. Zhao, H. Karoui, D. Bardelang, O. Ouari, S. Liu, Org. Biomol. Chem. 2018, 16, 3809-3815.
45- Supramolecular encapsulation and bioactivity modulation of a halonium ion by cucurbit[n]uril (n = 7, 8), H. Yin, Q. Huang, W. Zhao, D. Bardelang, D. Siri, X. Chen, S. M. Y. Lee, R. Wang, J. Org. Chem. 2018, 83, 4882–4887.
44- Nitroxide Radicals with Cucurbit[n]urils and Other Cavitands, O. Ouari, D. Bardelang, Isr. J. Chem. 2018, 58, 343–356.
43- A chameleonic dye adapts to various environments shining on macrocycles or peptide and polysaccharide aggregates, H. Yin, F. Dumur, Y. Niu, M. M. Ayhan, O. Grauby, W. Liu, C. Wang, D. Siri, R. Rosas, A. Tonetto, D. Gigmes, R. Wang, D. Bardelang, O. Ouari, ACS Appl. Mater. Interfaces 2017, 9, 33220-33228.
42- Supramolecular alleviation of cardiotoxicity of a small-molecule kinase inhibitor, X. Yang, Q. Huang, D. Bardelang, Q. Zhang, H. Hu, S. M. Y. Lee, R. Wang, Org. Biomol. Chem. 2017, 15, 8046-8053.
41- Synthesis and properties of a series of β-cyclodextrin/nitrone spin traps for improved superoxide detection, F. Poulhès, E. Rizzato, P. Bernasconi, R. Rosas, S. Viel, L. Jicsinszky, A. Rockenbauer, D. Bardelang, D. Siri, A. Gaudel-Siri, H. Karoui, M. Hardy, O. Ouari, Org. Biomol. Chem. 2017, 15, 6358-6366.
40- Concealing the Taste of the Guinness World’s Most Bitter Substance by a Synthetic Receptor, X. Yang, S. Li, Q. Zhang, Y. Zheng, D. Bardelang, R. Wang, Nanoscale 2017, 9, 10606-10609.
39- Fluorescence enhancement and pKa shift of a Rho kinase inhibitor by a synthetic receptor, H. Yin, L. Chen, B. Yang, D. Bardelang, C. Wang, S. M.-Y. Lee, R. Wang, Org. Biomol. Chem. 2017, 15, 4336-4343.
38- Alleviation of Hepatotoxicity of Arecoline (Areca alkaloid) by a Synthetic Receptor, S. Li, X. Yang, Y. Niu, G. L. Andrew, D. Bardelang, X. Chen, R. Wang, Chem. Select 2017, 2, 2219-2223.
37- Supramolecular formulation of nitidine chloride can alleviate its hepatotoxicity and improve its anticancer activity, W. Li, H. Yin, D. Bardelang, J. Xiao, Y. Zheng, R. Wang, Food Chem. Tox. 2017, 109, 923-929.
36- Encapsulation of AGE-breaker Alagebrium by Cucurbit[7]uril Improved the Stability of both its Carbonyl a-Hydrogen and Thiazolium C(2)-Hydrogen, S. Li, Y.-F. Ding, H. Yin, C. Wang, D. Bardelang, L.-H. Wang, R. Wang, Chem. Asian J. 2016, 11, 3126-3133.
35- Complexation of clofazimine by macrocyclic cucurbit[7]uril reduced its cardiotoxicity without affecting the antimycobacterial efficacy, S. Li, J. Y.-W. Chan, Y. Li, D. Bardelang, J. Zheng, W. W. Yew, D. P.-C. Chan, S. M.-Y. Lee, R. Wang, Org. Biomol. Chem. 2016, 14, 7563-7569.
34- Supramolecular encapsulation of benzocaine and its metabolite para-aminobenzoic acid by Cucurbit[7]uril, S. Li, H. Yin, G. Martinz, I. Wyman, D. Bardelang, D. H. Macartney, R. Wang, New J. Chem. 2016, 40, 3484-3490.
33- Novel Naphthalimide-amine Based Photoinitiators Operating under Violet and Blue LEDs and Usable for Various Polymerization Reactions and the Synthesis of Hydrogels, N. Zivic, J. Zhang, D. Bardelang, F. Dumur, P. Xiao, T. Jet, D.-L. Versace, C. Dietlin, F. Morlet-Savary, B. Graff, J. P. Fouassier, D. Gigmes, J. Lalevée, Polymer. Chem. 2016, 7, 418-429.
32- Supramolecular inhibition of neurodegeneration by a synthetic receptor, S. Li, H. Chen, X. Yang, D. Bardelang, I. W. Wyman, J. Wan, S. M. Y. Lee, R. Wang, ACS. Med. Chem. Lett. 2015, 6, 1174-1178.
31- EPR studies of the binding properties, guest dynamics and the inner space dimensions of a water-soluble resorcinarene capsule, M. M. Ayhan, G. Casano, H. Karoui, A. Rockenbauer, V. Monnier, M. Hardy, P. Tordo, D. Bardelang, O. Ouari, Chem.- Eur. J. 2015, 21, 16404-16410.
30- Comprehensive synthesis of monohydroxy-cucurbit[n]urils (n = 5, 6, 7, 8): high purity and high conversions, M. M. Ayhan, H. Karoui, M. Hardy, A. Rockenbauer, L. Charles, R. Rosas, K. Udachin, P. Tordo, D. Bardelang, O. Ouari, J. Am. Chem. Soc. 2015, 137, 10238-10245. Correction.
29- High binding yet accelerated guest rotation within a cucurbit[7]uril complex. Toward paramagnetic gyroscopes and rolling nanomachines, G. Casano, F. Poulhès, T. K. Tran, M. M. Ayhan, H. Karoui, D. Siri, A. Gaudel-Siri, A. Rockenbauer, G. Jeschke, D. Bardelang, P. Tordo, O. Ouari, Nanoscale 2015, 7, 12143-12150.
28- Structure Design of Naphthalimide Derivatives: Towards Versatile Photoinitiators for Near UV/Visible LEDs, 3D Printing and Water Soluble Photoinitiating systems, J. Zhang, F. Dumur, P. Xiao, B. Graff, D. Bardelang, D. Gigmes, J.-P. Fouassier, J. Lalevée, Macromolecules 2015, 48, 2054-2063.
27- Developmental and organ-specific toxicity of cucurbit[7]uril: in vivo study on zebrafish models, H. Chen, J. Chan, X. Yang, I. W. Wyman, D. Bardelang, D. H. Macartney, S. M. Y. Lee, R. Wang, RSC Adv. 2015, 5, 30067-30074.
26- Dinitroxide Biradical Crystals with Polar Order, C. Ysacco, M. Giorgi, P. Tordo, D. Bardelang, O. Ouari, Can. J. Chem. 2015, 93, 920-924.
25- Spin exchange monitoring of the strong positive homotropic allosteric binding of a tetraradical by a synthetic receptor in water, D. Bardelang, G. Casano, F. Poulhès, H. Karoui, J. Filippini, A. Rockenbauer, R. Rosas, V. Monnier, D. Siri, A. Gaudel-Siri, O. Ouari, P. Tordo, J. Am. Chem. Soc. 2014, 136, 17570-17577.
24- High field solid state 13C NMR spectroscopy of cucurbituril materials, D. Bardelang, A. Brinkmann, C. I. Ratcliffe, J. A. Ripmeester, V. V. Terskikh, K. A. Udachin, CrystEngComm 2014, 16, 3788-3795.
23- Hosting Various Guests Including Fullerenes and Free Radicals in Versatile Organic Paramagnetic bTbk Open Frameworks, D. Bardelang, M. Giorgi, V. Hornebecq, A. Stepanov, M. Hardy, E. Rizzato, V. Monnier, Md. B. Zaman, G. Chan, K. Udachin, G. Enright, O. Ouari, P. Tordo, Cryst. Growth Des. 2014, 14, 467-476.
22- Organic multishell isostructural host-guest crystals: fullerenes C60 inside a nitroxide open framework, D. Bardelang, M. Giorgi, C. Pardanaud, V. Hornebecq, E. Rizzato, P. Tordo, O. Ouari, Chem. Comm. 2013, 49, 3519-3521.
21- Perturbation induced formation of a 3D-network of microcrystals producing soft materials, D. Bardelang, M. Giorgi, V. Hornebecq, A. Stepanov, E. Rizzato, Md. B. Zaman, G. Chan, O. Ouari, P. Tordo, RSC Adv. 2012, 2, 5605-5609.
20- Size Reduction of CdSe/ZnS Quantum Dots by a Peptidic Amyloid Supergelator, Md. B. Zaman, D. Bardelang, M. Prakesch, D. M. Leek, J.-V. Naubron, G. Chan, X. Wu, J. A. Ripmeester, C. I. Ratcliffe, K. Yu, ACS Appl. Mater. Interfaces 2012, 4, 1178-1181.
19- Cucurbit[n]urils (n = 5 - 8): A Comprehensive Solid State Study, D. Bardelang, K. A. Udachin, D. M. Leek, J. Margeson, G. Chan, C. I. Ratcliffe, J. A. Ripmeester, Cryst. Growth Des. 2011, 11, 5598–5614.
18- Nanoscale assembly of photoluminescent quantum dots on the surface of calix[8]arene microcrystals, Md. B. Zaman, D. Bardelang, S. Lang, Md. R. Karim, X. Wu, Z. J. Jakubek, K. Udachin, C. I. Ratcliffe, J. A. Ripmeester, K. Yu, CrystEngComm 2011, 13, 3306-3309.
17- Photoluminescent quantum dots - cucurbituril nanocomposites, M. Li, Md. B. Zaman, D. Bardelang, X. Wu, D. Wang, J. C. Margeson, D. M. Leek, J. A. Ripmeester, C. I. Ratcliffe, Q. Lin, B. Yang, Kui Yu, Chem. Comm. 2009, 6807-6809.
16- Improving the trapping of superoxide radical with a beta-cyclodextrin-5-diethoxyphosphoryl-5-methyl-1-pyrroline-N-oxide (DEPMPO) conjugate, M. Hardy, D. Bardelang, H. Karoui, A. Rockenbauer, J.-P. Finet, L. Jicsinszky, R. Rosas, O. Ouari, P. Tordo, Chem.- Eur. J. 2009, 15, 11114-11118.
15- Probing cucurbituril assemblies in water with TEMPO-like nitroxides: A trinitroxide supraradical with spin-spin interactions, D. Bardelang, K. Banaszak, H. Karoui, A. Rockenbauer, M. Waite, K. Udachin, J. A. Ripmeester, C. I. Ratcliffe, O. Ouari, P. Tordo, J. Am. Chem. Soc. 2009, 131, 5402-5404.
14- Inclusion complexes of coumarin in cucurbiturils, R. Wang, D. Bardelang, M. Waite, K. A. Udachin, D. M. Leek, K. Yu, C. I. Ratcliffe, J. A. Ripmeester, Org. Biomol. Chem. 2009, 7, 2435-2439.
13- Ultrasound induced gelation: A paradigm shift, D. Bardelang, Soft Matter 2009, 5, 1969-1971.
12- EPR, NMR, and thermodynamic evidences for forced nuclear spin - electron spin interactions in the case of 1-phenyl-2-methylpropyl-1,1-dimethyl-2-nitroxide (TIPNO) appended permethylated-beta-cyclodextrin, E. G. Bagryanskaya, D. Bardelang, S. Chenesseau, J.-P. Finet, L. Jicsinszky, H. Karoui, S. R. A. Marque, K. Möbius, D. Polovyanenko, A. Savitsky, P. Tordo, Appl. Magn. Reson. 2009, 36, 181-194.
11- Interfacing supramolecular gels and quantum dots with ultrasound: smart photoluminescent dipeptide gels, D. Bardelang, B. Zaman, I. Moudrakovski, S. Pawsey, J. C. Margeson, D. Wang, X. Wu, J. A. Ripmeester, C. I. Ratcliffe, Kui Yu, Adv. Mater. 2008, 20, 4517-4520.
10- Single-crystal to single-crystal phase transition of cucurbit[5]uril hydrochloride hydrates: large water-filled channels transforming to layers of unusual stability, D. Bardelang, K. A. Udachin, R. Anedda, I. Moudrakovski, D. M. Leek, J. A. Ripmeester, C. I. Ratcliffe, Chem. Comm. 2008, 44, 4927-4929.
9- Unusual sculpting of dipeptide particles by ultrasound induces gelation, D. Bardelang, F. Camerel, J. C. Margeson, D. M. Leek, M. Schmutz, B. Zaman, K. Yu, R. Ziessel, C. I. Ratcliffe, J. A. Ripmeester, J. Am. Chem. Soc. 2008, 130, 3313-3315.
8- New organogelators based on cyclotriveratrylene platforms bearing 2-dimethylacetal-5-carbonylpyridine fragments, D. Bardelang, F. Camerel, M. Schmutz, R. Ziessel, M. J. Hannon, J. Mater. Chem. 2008, 18, 489-494.
7- Highly symmetric columnar channels in metal free cucurbit[n]uril crystals (n = 6, 8), D. Bardelang, K. A. Udachin, D. M. Leek, J. A. Ripmeester, CrystEngComm 2007, 9, 973-975.
6- Sodium chains as core nanowires for gelation of organic solvents from a functionalized nicotinic acid and its sodium salt, D. Bardelang, F. Camerel, A. C. G. Hotze, B. Kariuki, B. Paik, M. Schmutz, R. Ziessel, M. J. Hannon, Chem.- Eur. J. 2007, 13, 9277-9285.
5- PBN-type nitrone bound b-cyclodextrins: syntheses, thermokinetics of self-inclusion and applications for superoxide spin-trapping, D. Bardelang, J.-P. Finet, L. Jicsinszky, H. Karoui, S. R. A. Marque, A. Rockenbauer, R. Rosas, L. Charles, V. Monnier, P. Tordo, Chem.- Eur. J. 2007, 13, 9344-9354.
4- Nitroxide bound b-cyclodextrin: Is there an inclusion complex?, D. Bardelang, A. Rockenbauer, L. Jicsinszky, J.-P. Finet, H. Karoui, S. Lambert, S. R. A. Marque, P. Tordo, J. Org. Chem. 2006, 71, 7657-7667.
3- Inclusion complexes of EMPO derivatives with 2,6-di-O-methyl-b-cyclodextrin: synthesis, NMR and EPR investigations for enhanced superoxide detection, D. Bardelang, A. Rockenbauer, H. Karoui, J.-P. Finet, I. Biskupska, K. Banaszak, P. Tordo, Org. Biomol. Chem. 2006, 4, 2874-2882.
2- Inclusion complexes of PBN-type nitrone spin traps and their superoxide spin adducts with cyclodextrin derivatives: parallel determination of the association constants by NMR titrations and 2D-EPR simulations, D. Bardelang, A. Rockenbauer, J.-P. Finet, H. Karoui, P. Tordo, J. Phys. Chem. B 2005, 109, 10521-10530.
1- NMR investigations of the beta-cyclodextrin inclusion of (alpha-phenyl-N-tert-butylnitrone) analogues, D. Bardelang, J.-L. Clément, J.-P. Finet, H. Karoui, P. Tordo, J. Phys. Chem.B 2004, 108, 8054-8061.
