Prof. Jean RODRIGUEZ
Prof.
Jean
RODRIGUEZ
AMU iSm2 Service 531
Campus Scientifique de St Jérôme
13397
Marseille cedex 20
Phone number :
Fax :
0491 28 9187
Date of entry :
01/01/2008
Career path :
1984 : PhD of Speciality at the University of Aix-Marseille
1984 : Recruted by the CNRS as Attaché de Recherche
1987 : PhD in Sciences at the University of Aix-Marseille
1988 : Postdoctoral reseach associate, University of California (Berkeley), supervisor: Prof K.P.C. Vollhardt
1989 : Promoted Chargé de Recherche de 1ère classe at CNRS
1992 : Habilitation at the University of Aix-Marseille
1998 : Promoted Directeur de Recherche at the CNRS
2002 : Nominated full Professor at the University of Aix-Marseille
Honour :
1998 : Prize from ACROS-French Chemical Society in organic chemistry
2009 : Prize from the Société Chimique de France, Division Chimie Organique
2013 : Member of the Editorial Board of European Journal of Organic Chemistry
2013 : Distinguished Senior Member of the Société Chimique de France
2021 : Grand Prix de l'Académie des Sciences Emile Jungfleisch
Teachings :
Bachelor Degree in Chemistry
*Ionic and Polar Rearrangements in Organic Synthesis
Master Degree in Chemistry
*Strategies in Synthetic Organic Chemistry (Retrosynthetic analysis, Total synthesis, Protection and Deprotection of functional groups)
*New Selective Multiple Bond-Forming Transformations (Metallo- and Organocatalyzed Consecutive, Domino and Multicomponent reactions)
*Recent Applications of enantioselective metallo- and organocatalysis in Organic Synthesis
Collaborations and groups :
Dr Muriel AMATORE, Assitant Professor
Dr Damien BONNE, Assistant Professor
Dr Xavier BUGAUT, Full professor
Dr Thierry CONSTANTIEUX, Full Professor
Dr Yoann COQUEREL, Associate Researcher from the CNRS
Dr Adrien QUINTARD, Associate Researcher from the CNRS
Dr. Manuel BARDAY, Postdoctoral Research Associate (2022)
Dr. Expédite Yen-PON, Postdoctoral Research Associate (2022)
Pierre BOUILLAC, PhD student (2019-2022)
Birane DIOP, PhD student (2022)
Arthur GAUCHERAND, PhD student (2020-2023)
Na SHAO, PhD student (2020-2024)
Administrative responsabilities :
1999-2007 : Member of Bureau National de la S F C, Division Chimie Organique
2000-2006 : Expert auprès du ministère dans le cadre de la MSTP4
2004-2007 : Director of the Reseach Unit SYMBIO
2006-2011 : Chargé de Mission à l'Institut de chimie du CNRS (section 12)
2008- Present : Director of the Institut des Sciences Moléculaires de Marseille (iSm2)
Publications (210)
Reference
Graphical abstract
HAL
Multicatalytic Enantioselective Borrowing Hydrogen δ-Lactonization Strategy from β-Keto Esters and Allylic Alcohols
Adrien Quintard, Mylène Roudier, Jean Rodriguez, Synthesis: Journal of Synthetic Organic Chemistry, 2018, 50, 785 - 792. <hal-01700677>
✓
Weinreb β-Ketoamides in Enantioselective Organocatalysis: A Balance between Reactivity and Selectivity
Haiying Du, Yohan Dudognon, Jean Rodriguez, Thierry Constantieux, Xavier Bugaut, SYNLETT, 2018. <hal-01723120>
✓
Discovery of Eco-Compatible Synthetic Paths by a Multi-Catalysis Approach
Jean Rodriguez, Adrien Quintard, CHIMIA, 2018, 72, 580-583. <hal-01890347>
✓
Organocatalytic Enantioselective Synthesis of Tetrahydropyridines
Yohan Dudognon, Jean Rodriguez, Thierry Constantieux, Xavier Bugaut, European Journal of Organic Chemistry, 2018, 2018, 2432-2442. <hal-01969953>
✓
Modular Enantioselective Synthesis of an Advanced Pentahydroxy Intermediate of Antimalarial Bastimolide A and of Fluorinated and Chlorinated Analogues
Adrien Quintard, Céline Sperandio, Jean Rodriguez, Organic Letters, 2018, 20, 5274 - 5277. <hal-01871735>
✓
Enantioselective syntheses of atropisomers featuring a five-membered ring
Damien Bonne, Jean Rodriguez, Chemical Communications, 2017, 53, 12385-12393. <hal-01687197>
✓
Organocatalytic Activation of Diethyl Glutaconate for the Diastereo- and Enantioselective Assembly of NH-Free 2,3,4-Trisubstituted Pyrrolidines
Adrien Quintard, Jean Rodriguez, Organic Letters, 2017, 19, 722-725. <hal-01533766>
✓
Chiral Nanographene Propeller Embedding Six Enantiomerically Stable [5]Helicene Units
Veronika Berezhnaia, Myriam Roy, Nicolas Vanthuyne, Marc Villa, Jean Naubron, Jean Rodriguez, Yoann Coquerel, Marc Gingras, Journal of the American Chemical Society, 2017, 139, 18508-18511. <hal-01683221>
✓
Expeditious Synthesis of Enantioenriched Tetrahydropyrans via Chemoselective C−N bond Cleavage of Aza-Oxa-Bicyclo[3.2.1]Octanes
Cecilia Sasso D 'Elia, Sébastien Goudedranche, Thierry Constantieux, Marco Bella, Damien Bonne, Jean Rodriguez, Advanced Synthesis and Catalysis, 2017, 359, 3638-3641. <hal-01687211>
✓
Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy
Vivek S Raut, Marion Jean, Nicolas Vanthuyne, Christian Roussel, Thierry Constantieux, Cyril Bressy, Xavier Bugaut, Damien Bonne, Jean Rodriguez, Journal of the American Chemical Society, 2017, 139, 2140-2143. <hal-01533761>
✓
Pages
Books (3)
Reference
Graphical abstract
HAL
Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis
Eds.: J. Rodriguez, D. Bonne, John Wiley & Sons, Inc., Hoboken, NJ, USA, 2015.
✖
Jean Rodriguez, Damien Bonne. Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis. John Wiley & Sons, 2015, 978-1-118-67271-6. ⟨hal-01323433⟩
✖
1-Nitrocyclohexene
David Pierrot, Damien Bonne, Jean Rodriguez 2014, e-EROS Encyclopedia of Reagents for Organic Synthesis. 15.
✖
Chapters of books (9)
Reference
Graphical abstract
HAL
Yoann Coquerel, Jean Rodriguez. The Wolff Rearrangement: Tactics, Strategies and Recent Applications in Organic Synthesis. Molecular Rearrangements in Organic Synthesis, Johne Wiley & Sons, pp.59-84, 2015, 978-1-118-34796-6. ⟨hal-01224316⟩
✖
1,3-Dicarbonyls in Multicomponent Reactions
X. Bugaut, T. Constantieux, Y. Coquerel, J. Rodriguez, In Multicomponent Reactions in Organic Synthesis, Eds.: J. Zhu, Q. Wang, M.-X. Wang, Wiley-VCH, Weinheim, 2014, Chap. 5, pp 109-158.
✖
Xavier Bugaut, Thierry Constantieux, Yoann Coquerel, Jean Rodriguez. 1,3-Dicarbonyls in Multicomponent Reactions. J. Zhu, Q. Wang, M.-X. Wang. Multicomponent Reactions in Organic Synthesis, Wiley-VCH, Weinheim, pp.109-158, 2014, 978-3-527-33237-3. ⟨hal-01133604⟩
✖
Reactions Involving an alpha,beta-Unsaturated Compound as Electrophilic Component with the Michael Addition as the Key Step
J. Rodriguez, D. Bonne, Y. Coquerel, T. Constantieux, dans 'Multicomponent Reactions 2', 'Science of Synthesis Reference Library', T. J. J. Müller, Ed., Thieme, Stuttgart, 2013, Chap. 2.1.1, p. 1-36.
✖
Stereoselective Multicomponent Reactions: from Simple 1,3-Dicarbonyls to Functionalized Chiral Heterocycles
D. Bonne, Y. Coquerel, T. Constantieux, J. Rodriguez in Targets in Heterocyclic Systems - Chemistry and Properties, Vol. 15, Eds.: O. A. Attanasi, D. Spinelli, Societa? Chimica Italiana, Roma, 2011, pp. 140-163.
✖
Utilisation des dérivés 1,3-dicarbonylés dans les réactions domino et multicomposé
Damien Bonne, Thierry Constantieux, Yoann Coquerel, Jean Rodriguez Techniques de l'Ingénieur 2010, CHV2210
✖
Damien Bonne, Thierry Constantieux, Yoann Coquerel, Jean Rodriguez. Utilisation des dérivés 1,3-dicarbonylés dans les réactions domino et multicomposé. Ideas in Chemistry and Molecular Sciences: Advances in Synthetic Chemistry, pp.CHV2210, 2010. ⟨hal-00680619⟩
✖
Yoann Coquerel, Thomas Boddaert, Marc Presset, Damien Mailhol, Jean Rodriguez. Multiple Bond-Forming Transformations: the Key Concept towards Eco-compatible Synthetic Organic Chemistry. Ideas in Chemistry and Molecular Sciences, Vol.1 Advances in synthetic chemistry, Wiley-VCH, Weinheim, pp.187-202, 2010, 3527325395. ⟨hal-00681017⟩
✖
Maria del Mar Sanchez Duque, Christophe Allais, Nicolas Isambert, Thierry Constantieux, Jean Rodriguez. beta-diketo building blocks for MCRs-based syntheses of heterocycles. Topics in Heterocyclic Chemistry, Springer, pp.227-277, 2010, ⟨10.1007/7081_2010_26⟩. ⟨hal-00680508⟩
✓
Patents (1)
Reference
Graphical abstract
HAL
Adrien Quintard, Céline Sperandio, Jean Rodriguez. NOVEL FLUORINATED POLYOLS AND THEIR USE AS ORGANOGELATORS. France, Patent n° : WO/2019/238582. 2019. ⟨hal-02878986⟩
✖
1984 : PhD of Speciality at the University of Aix-Marseille
1984 : Recruted by the CNRS as Attaché de Recherche
1987 : PhD in Sciences at the University of Aix-Marseille
1988 : Postdoctoral reseach associate, University of California (Berkeley), supervisor: Prof K.P.C. Vollhardt
1989 : Promoted Chargé de Recherche de 1ère classe at CNRS
1992 : Habilitation at the University of Aix-Marseille
1998 : Promoted Directeur de Recherche at the CNRS
2002 : Nominated full Professor at the University of Aix-Marseille
1998 : Prize from ACROS-French Chemical Society in organic chemistry
2009 : Prize from the Société Chimique de France, Division Chimie Organique
2013 : Member of the Editorial Board of European Journal of Organic Chemistry
2013 : Distinguished Senior Member of the Société Chimique de France
2021 : Grand Prix de l'Académie des Sciences Emile Jungfleisch
Bachelor Degree in Chemistry
*Ionic and Polar Rearrangements in Organic Synthesis
Master Degree in Chemistry
*Strategies in Synthetic Organic Chemistry (Retrosynthetic analysis, Total synthesis, Protection and Deprotection of functional groups)
*New Selective Multiple Bond-Forming Transformations (Metallo- and Organocatalyzed Consecutive, Domino and Multicomponent reactions)
*Recent Applications of enantioselective metallo- and organocatalysis in Organic Synthesis
Dr Muriel AMATORE, Assitant Professor
Dr Damien BONNE, Assistant Professor
Dr Xavier BUGAUT, Full professor
Dr Thierry CONSTANTIEUX, Full Professor
Dr Yoann COQUEREL, Associate Researcher from the CNRS
Dr Adrien QUINTARD, Associate Researcher from the CNRS
Dr. Manuel BARDAY, Postdoctoral Research Associate (2022)
Dr. Expédite Yen-PON, Postdoctoral Research Associate (2022)
Pierre BOUILLAC, PhD student (2019-2022)
Birane DIOP, PhD student (2022)
Arthur GAUCHERAND, PhD student (2020-2023)
Na SHAO, PhD student (2020-2024)
1999-2007 : Member of Bureau National de la S F C, Division Chimie Organique
2000-2006 : Expert auprès du ministère dans le cadre de la MSTP4
2004-2007 : Director of the Reseach Unit SYMBIO
2006-2011 : Chargé de Mission à l'Institut de chimie du CNRS (section 12)
2008- Present : Director of the Institut des Sciences Moléculaires de Marseille (iSm2)
| Reference | Graphical abstract | HAL |
|---|---|---|
|
Multicatalytic Enantioselective Borrowing Hydrogen δ-Lactonization Strategy from β-Keto Esters and Allylic Alcohols |
|
✓ |
|
Weinreb β-Ketoamides in Enantioselective Organocatalysis: A Balance between Reactivity and Selectivity |
|
✓ |
|
Discovery of Eco-Compatible Synthetic Paths by a Multi-Catalysis Approach |
|
✓ |
|
Organocatalytic Enantioselective Synthesis of Tetrahydropyridines |
|
✓ |
|
Modular Enantioselective Synthesis of an Advanced Pentahydroxy Intermediate of Antimalarial Bastimolide A and of Fluorinated and Chlorinated Analogues |
|
✓ |
|
Enantioselective syntheses of atropisomers featuring a five-membered ring |
|
✓ |
|
Organocatalytic Activation of Diethyl Glutaconate for the Diastereo- and Enantioselective Assembly of NH-Free 2,3,4-Trisubstituted Pyrrolidines |
|
✓ |
|
Chiral Nanographene Propeller Embedding Six Enantiomerically Stable [5]Helicene Units |
|
✓ |
|
Expeditious Synthesis of Enantioenriched Tetrahydropyrans via Chemoselective C−N bond Cleavage of Aza-Oxa-Bicyclo[3.2.1]Octanes |
|
✓ |
|
Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy |
|
✓ |
Pages
| Reference | Graphical abstract | HAL |
|---|---|---|
|
Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis |
|
✖ |
|
Jean Rodriguez, Damien Bonne. Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis. John Wiley & Sons, 2015, 978-1-118-67271-6. ⟨hal-01323433⟩ |
|
✖ |
|
1-Nitrocyclohexene |
|
✖ |
| Reference | Graphical abstract | HAL |
|---|---|---|
|
Yoann Coquerel, Jean Rodriguez. The Wolff Rearrangement: Tactics, Strategies and Recent Applications in Organic Synthesis. Molecular Rearrangements in Organic Synthesis, Johne Wiley & Sons, pp.59-84, 2015, 978-1-118-34796-6. ⟨hal-01224316⟩ |
|
✖ |
|
1,3-Dicarbonyls in Multicomponent Reactions |
|
✖ |
|
Xavier Bugaut, Thierry Constantieux, Yoann Coquerel, Jean Rodriguez. 1,3-Dicarbonyls in Multicomponent Reactions. J. Zhu, Q. Wang, M.-X. Wang. Multicomponent Reactions in Organic Synthesis, Wiley-VCH, Weinheim, pp.109-158, 2014, 978-3-527-33237-3. ⟨hal-01133604⟩ |
|
✖ |
|
Reactions Involving an alpha,beta-Unsaturated Compound as Electrophilic Component with the Michael Addition as the Key Step |
|
✖ |
|
Stereoselective Multicomponent Reactions: from Simple 1,3-Dicarbonyls to Functionalized Chiral Heterocycles |
|
✖ |
|
Utilisation des dérivés 1,3-dicarbonylés dans les réactions domino et multicomposé |
|
✖ |
|
Damien Bonne, Thierry Constantieux, Yoann Coquerel, Jean Rodriguez. Utilisation des dérivés 1,3-dicarbonylés dans les réactions domino et multicomposé. Ideas in Chemistry and Molecular Sciences: Advances in Synthetic Chemistry, pp.CHV2210, 2010. ⟨hal-00680619⟩ |
|
✖ |
|
Yoann Coquerel, Thomas Boddaert, Marc Presset, Damien Mailhol, Jean Rodriguez. Multiple Bond-Forming Transformations: the Key Concept towards Eco-compatible Synthetic Organic Chemistry. Ideas in Chemistry and Molecular Sciences, Vol.1 Advances in synthetic chemistry, Wiley-VCH, Weinheim, pp.187-202, 2010, 3527325395. ⟨hal-00681017⟩ |
|
✖ |
|
Maria del Mar Sanchez Duque, Christophe Allais, Nicolas Isambert, Thierry Constantieux, Jean Rodriguez. beta-diketo building blocks for MCRs-based syntheses of heterocycles. Topics in Heterocyclic Chemistry, Springer, pp.227-277, 2010, ⟨10.1007/7081_2010_26⟩. ⟨hal-00680508⟩ |
|
✓ |
| Reference | Graphical abstract | HAL |
|---|---|---|
|
Adrien Quintard, Céline Sperandio, Jean Rodriguez. NOVEL FLUORINATED POLYOLS AND THEIR USE AS ORGANOGELATORS. France, Patent n° : WO/2019/238582. 2019. ⟨hal-02878986⟩ |
|
✖ |