Institut des Sciences Moléculaires de Marseille Université Paul cézanne Aix Marseille III
               
       

 

Hervé Clavier

Dr. Hervé CLAVIER

AMU iSm2 Service 462
Campus Scientifique de St Jérôme
13397 Marseille cedex 20

 

Téléphone : 0491 28 8649

Fax : 0491 28 2742

Courriel : herve.clavier{noSPAM}univ-amu.fr

Autre site Web :

 

Parcours

1999-2002 ENSC-Rennes
2001-2002 DEA, Université de Rennes I
2002-2005 Doctorat, ENSCR - Université de Rennes I, Dr. J.-C. Guillemin, Dr. M. Mauduit
2006-2008 Post-doctorat, ICIQ (Tarragone, Espagne), Prof. S. P. Nolan
2009 Chercheur senior, University of St Andrews (UK), Prof. S. P. Nolan
Oct 2009 Chargé de Recherche CNRS, Université Cezanne, Aix-Marseille III

Enseignements

Thématiques

Catalyse par des métaux de transition
Réactions de cycloaddtions et de cyclisations
Catalyse énantiosélective

Responsabilités administratives

Publications

Title - Authors - Journal
Graphical Abstracts
Chemodivergent palladium-catalyzed processes: role of versatile ligands

P. Nava, H. Clavier, Y. Gimbert, L. Giordano, G. Buono, S. Humbel, ChemCatChem 2015, 7, 3848 ? 3854

Seven- and eight-membered carbocycles

G. Buono, H. Clavier, L. Giordano, A. Tenaglia, in ?Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis? J. Rodriguez, D. Bonne, Eds., John Wiley & Sons, Hoboken, 2015, 211-240.

Preparation of Vinylcyclopropanes by Sodium Mediated Reductive Isomerization of Methylenecyclopropanes

K. Le Jeune, S. Chevallier-Michaud, D. Gatineau, L. Giordano, A. Tenaglia, Herve? Clavier, J. Org. Chem. 2015, 80, 8821-8829.

Recent Developments in the [5+2] Cycloaddition

H. Clavier, H. Pellissier, in ?Methods and Applications of Cycloaddition Reactions in Organic Syntheses? N. Nishiwaki, Ed., John Wiley & Sons, Hoboken, 2014, 631-654.

Metal-Catalyzed Asymmetric Nucleophilic Addition to Electron-Deficient Alkenes

M. Mauduit, O. Baslé, H. Clavier, C. Crévisy, A. Denicourt-Nowicki, in ?Comprehensive Organic Synthesis?, 2nd Edition Volume 4, G. A. Molander, P. Knochel, Eds., Elsevier, Oxford, 2014, 189-341.

New Secondary Phosphine Oxide-Gold(I) Complexes and their Application in Catalysis

F. Schröder, C. Tugny, E. Salanouve, H. Clavier, L. Giordano, D. Moraleda, Y. Gimbert, V. Mouriès-Mansuy, J.-P. Goddard, L. Fensterbank, Organometallics 2014, 33, 4051-4056.

Palladium-catalyzed addition of 1,3-diones to ynamides: an entry to alkoxy-substituted enamides

L. V. Graux, H. Clavier, G. Buono, ChemCatChem 2014, 6, 2544-2548.

Enantioselective Cobalt-Catalyzed Transformations

H. Pellissier, H. Clavier, Chem. Rev. 2014, 114, 2775-2823.

Palladium-Mediated [2+1] Cycloaddition of Norbornene Derivatives with Ynamides

H. Clavier, A. Lepronier, N. Bengobesse-Mintsa, D. Gatineau, H. Pellissier, L. Giordano, A. Tenaglia, G. Buono, Adv. Synth. Catal. 2013, 355, 304-308.

Palladium-mediated phosphine-oriented chemoselective bis allylic alkylation leading to spirocarbocycles

H. Clavier, L. Giordano, A. Tenaglia, Angew. Chem. Int. Ed. 2012, 51, 8648-8651

Recent Developments in Enantioselective Metal-Catalyzed Domino Reactions

Hervé Clavier and Hélène Pellissier Adv. Synth. Catal. 2012, 354, 3347-3403.

Steric and Electronic Parameters Characterizing Bulky and Electron-Rich Dialkylbiarylphosphines

O. Diebolt, G. C. Fortman, H. Clavier, A. M. Z. Slawin, E. C. Escudero-Adán, J. Benet-Buchholz, S. P. Nolan, Organometallics 2011, 30, 1668-1676.

A Regio- and Diastereoselective Platinum-Catalyzed Tandem [2+1]/[3+2] Cycloaddition Sequence

T. Achard, A. Lepronier, Y. Gimbert, H. Clavier, L. Giordano, A. Tenaglia, G. Buono, Angew. Chem. Int. Ed. 2011, 50, 3552-3556.

Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand

C. A. Urbina-Blanco, A. Leitgeb, C. Slugovc, X. Bantreil, H. Clavier, A. M. Z. Slawin, S. P. Nolan, Chem. Eur. J. 2011, 17, 5045-5053.

Synthesis, Characterization, and Reactivity of Cationic Gold(I) ?-Diimine Complexes

P. de Frémont, H. Clavier, V. Rosa, T. Avilés, P. Braunstein, Organometallics 2011, 30, 2241-2251.

Highly selective cobalt-mediated [6+2] cycloaddition of cycloheptatriene and allenes

H. Clavier, K. Le Jeune, I. De Riggi, A. Tenaglia, G. Buono, Org. Lett. 2011, 13, 308-311.

Ring-Rearrangement Metathesis (RRM) Mediated by Ruthenium-Indenylidene Complexes

H. Clavier, J. Broggi, S. P. Nolan, Eur J. Org. Chem. 2010, 937-943.

Ruthenium Olefin Metathesis Catalysts Bearing N-Naphthyl-Substituted N-Heterocyclic Carbenes

L. Vieille-Petit, H. Clavier, M. Gatti, X. Luan, A. Linden, S. Blumentritt, S. P. Nolan, R. Dorta, Organometallics 2010, 29, 775-788.

Chemioselective Olefin Metathesis Transformations Mediated by Ruthenium Complexes

S. P. Nolan, H. Clavier, Chem. Soc. Rev. 2010, 39, 3305-3316.

Metathesis versatility of ruthenium-indenylidene complexes induced by phosphine tuning

J. Broggi, C. A. Urbina-Blanco, H. Clavier, A. Leitgeb, C. Slugovc, A. M. Z. Slawin, S. P. Nolan, Chem. Eur. J. 2010, 16, 9215-9225.

Backbone tuning in indenylidene-ruthenium complexes bearing an unsaturated N-heterocyclic carbene

C. A. Urbina-Blanco, X. Bantreil, H. Clavier, A. M. Z. Slawin, S. P. Nolan, Belstein J. Org. Chem. 2010, 6, 1220-1226.

Chemodivergent Metathesis of Dienynes Catalyzed by Ruthenium-Indenylidene Complexes: An Experimental and Computational Study

H. Clavier, A. Correa, E. C. Escudero-Adán, J. Benet-Buchholz, L. Cavallo, S. P. Nolan, Chem. Eur. J. 2009, 15, 10244-10254.

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)IrCl(CO)2] System

R. A. Kelly III, H. Clavier, S. Guidice, N. M. Scott, E. D. Stevens, J. Bordner, I. Samardjiev, C. D. Hoff, L. Cavallo, S. P. Nolan, Organometallics 2008, 27, 202-210.

Ruthenium-indenylidene complexes: scope in cross metathesis transformations

F. Boeda, X. Bantreil, H. Clavier, S. P. Nolan, Adv. Synth. Catal. 2008, 350, 2959-2966.

Ruthenium-Indenylidene Complexes: Powerful Tools for Metathesis Transformations

F. Boeda, H. Clavier, S. P. Nolan, Chem. Commun. 2008, 2726-2740.

Acetamide Group-Containing Hoveyda-Grubbs Type Complexes: Synthesis and Activity in Olefin Metathesis Transformations

D. Rix, F. Caïjo, I. Laurent, F. Boeda, H. Clavier, S. P. Nolan,M. Mauduit, J. Org. Chem. 2008, 73, 4225-4228.

Clean, Green and Sustainable Chemistry: Applicable Concepts in Olefin Metathesis

H. Clavier, K. Grela, A. Kirschning, M. Mauduit, S. P. Nolan, Angew. Chem. Int. Ed. 2007, 46, 6786-6801.

Copper catalyzed asymmetric conjugate addition of Grignard reagents to trisubstituted enones. Constructoin of all quaternary chiral centers

D. Martin, S. Kehrli, M. d?Augustin, H. Clavier, M. Mauduit, A. Alexakis, J. Am. Chem. Soc. 2006, 128, 8416-8417.

Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents to Trisubstituted Enones. Construction of All-Carbon Quaternary Chiral Centers

David Martin, Stefan Kehrli, Magali d'Augustin, Hervé Clavier, Marc Mauduit, Alexandre Alexakis, J. Am. Chem. Soc., 2006, 128, 8416-8417

New bidentate alkoxy-NHC ligands for enantioselective copper-catalysed conjugate addition

H. Clavier, L. Coutable, J.-C. Guillemin, M. Mauduit, Tetrahedron: Asymmetry 2005, 16, 921-924

Design and synthesis of imidazolinium salts derived from (L)-valine. Investigation of their potential in chiral molecular recognition

H. Clavier, L. Boulanger, N. Audic, L. Toupet, M. Mauduit, J.-C. Guillemin, Chem. Commun. 2004, 1224-1225.

An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Metathesis in Ionic Liquids

N. Audic, H. Clavier, M. Mauduit, J.-C. Guillemin, J. Am. Chem. Soc. 2003, 125, 9248-9249

 

   
   

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